Skip to main content
SpringerLink
Log in

Preparation of Hybrid Material Based of PANI with SiO2 and Its Adsorption of Phenol from Aqueous Solution

  • Composites
  • Published:
Polymer Science, Series B Aims and scope Submit manuscript

Abstract

PANI and PANI-SiO2 were prepared by chemical oxidative polymerization in acidic medium of hydrochloric acid (1 M) using ammonium persulfate as oxidant. The developed adsorbents were characterized using various analytical techniques such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and physical adsorption of gases. To further explore the advantages of these materials for real applications, we investigated the electrochemical properties of these samples electrodes. The efficiency of PANI, SiO2 and PANI-SiO2 for the adsorptive removal of phenol (Ph) from aqueous solutions has been evaluated with respect of several experimental conditions. These latter has to do with the effect of contact time and the effect of pH. The experimental data were analyzed by the Langmuir and Freundlich isotherm models. The Langmuir isotherm fits the experimental data very well due to the homogeneous distribution of active sites onto adsorbents surface. The kinetics study revealed that adsorption of Ph onto three samples follows the pseudo-second order kinetic model.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. J. Collins, M. J. Kotterman, J. A. Field, and A. D. Dobson, Appl. Environ. Microbiol. 62, 4563 (1996).

    CAS  PubMed  PubMed Central  Google Scholar 

  2. A. Majcherczyk, C. Johannes, and A. Hüttermann, Enzyme Microb. Technol. 22, 335 (1998).

    Article  CAS  Google Scholar 

  3. H. Ali, Water, Air Soil Pollut. 213, 251 (2010).

    Article  CAS  Google Scholar 

  4. C. Janardanan and V. P. Vinisha, Int. J. Adv. Chem. 2, 6 (2014).

    Google Scholar 

  5. R. Ansari, Russ. J. Electrochem. 41, 950 (2005).

    Article  CAS  Google Scholar 

  6. G. G. Wallac, G. M. Sprinks, L. K. Magure, and P. Teasdale, Handbook of Conductive Eectroactive Polymers: Intelligent Materials Systems, 2nd ed. (CRC Press, New York, 2003).

    Google Scholar 

  7. S. Bhadraa, D. Khastgir, N. K. Singha, and J. H. Lee, Prog. Polym. Sci. 34, 783 (2009).

    Article  CAS  Google Scholar 

  8. S. Palaniappan and A. John, Prog. Polym. Sci. 33, 732 (2008).

    Article  CAS  Google Scholar 

  9. A. Marican, V. C. Sánchez, A. John, V. F. Laurie, and L. S. Santos, Food Chem. 159, 486 (2014).

    Article  CAS  PubMed  Google Scholar 

  10. L. S. Santos, V. F. Laurie, J. Amalraj, V. C. Sánchez, and F. Nachtigall, US Patent No. 8927042 (2015).

    Google Scholar 

  11. P. C. Ashley, M. J. Joseph, and P. V. Mohanan, Food Chem. 127, 1808 (2011).

    Article  CAS  Google Scholar 

  12. The New Frontiers of Organic and Composite Nanotechnology, Ed. by V. Erokhin, M. Ram, and Ö. Yavuz, (Elsevier, London, 2008), p. 143.

  13. M. Sivakumar and A. A. Gedanken, Synth. Met. 148, 301 (2005).

    Article  CAS  Google Scholar 

  14. H. Zengin, W. Zhou, J. Jin, R. Czerw, J. D. W. Smith, and L. Echegoyen, Adv. Mater. 14, 1480 (2002).

    Article  CAS  Google Scholar 

  15. N. Qingxin, P. Zengyuan, L. Dawei, Z. Huimin, H. Fenglin, C. Yibing, and W. Qufu, Colloids Surf., A 537, 532 (2018).

    Article  CAS  Google Scholar 

  16. J. Stejskal and I. Sapurina, Pure Appl. Chem. 77, 815 (2005).

    Article  CAS  Google Scholar 

  17. J. Stejskal, M. Trchová, S. Fedorova, I. Sapurina, and J. Zemek, Langmuir 19, 3013 (2003).

    Article  CAS  Google Scholar 

  18. J. Stejskal, O. Quadrat, I. Sapurina, J. Zemek, A. Drelinkiewicz, M. HasikeIvo, and K. J. Prokeš, Eur. Polym. J. 38, 631 (2002).

    Article  CAS  Google Scholar 

  19. S. Benyakhou, A. Belmokhtar, A. Zehhaf, and A. Benyoucef, J. Mol. Struct. 1150, 580 (2017).

    Article  CAS  Google Scholar 

  20. F. Chouli, I. Radja, E. Morallon, and A. Benyoucef, Polym. Compos. 38, E254 (2017).

    Article  CAS  Google Scholar 

  21. S. Benykhlef, A. Bekhoukh, R. Berenguer, A. Benyoucef, and E. Morallon, Colloid Polym. Sci. 294, 1877 (2016).

    Article  CAS  Google Scholar 

  22. A. Zehhaf, A. Benyoucef, C. Quijada, S. Taleb, and E. Morallon, Int. J. Environ. Sci. Technol. 12, 595 (2015).

    Article  CAS  Google Scholar 

  23. F. J. G. Mateos, I. Moulefera, J. M. Rosas, A. Benyoucef, J. R. Mirasol, and T. Cordero, Catalysts 7, 308 (2017).

    Article  CAS  Google Scholar 

  24. V. S. Rao, K. S. Rao, M. N. Rao, and U. S. Bora, Asian J. Biochem. Pharm. Res. 2, 567 (2011).

    Google Scholar 

  25. M. Mekhloufi, A. Zehhaf, A. Benyoucef, C. Quijada, and E. Morallon, Environ. Monit. Assess. 185, 10365 (2013).

    Article  CAS  PubMed  Google Scholar 

  26. A. R. Kul and H. Koyunchu, J. Hazard. Mater. 179, 332 (2010).

    Article  CAS  PubMed  Google Scholar 

  27. Y. S. Ho and G. McKay, Process Biochem. 34, 451 (1999).

    Article  CAS  Google Scholar 

  28. S. J. Gregg and K. S. W. Sing, Adsorption, Surface Area and Porosity, 2nd ed. (Academic Press, London, 1982), pp. 3–12.

    Google Scholar 

  29. C. G. V. Burgess, D. H. Everett, and S. Nuttall, Pure Appl. Chem. 61, 1845 (1989).

    Article  CAS  Google Scholar 

  30. A. S. Kumar, H. Bhandari, C. Sharma, F. Khatoon, and S. K. Dhawan, Polym. Int. 62, 1192 (2013).

    Article  CAS  Google Scholar 

  31. K. C. Sajjan, A. S. Roy, A. Parveen, and S. Khasim, J. Mater. Sci.: Mater. Electron. 25, 1237 (2014).

    CAS  Google Scholar 

  32. Y. G. Wang, H. Q. Li, and Y. Y. Xia, Adv. Mater. 18, 2619 (2006).

    Article  CAS  Google Scholar 

  33. C. C. Hu and C. H. Chu, Mater. Chem. Phys. 65, 329 (2000).

    Article  CAS  Google Scholar 

  34. M. Wawrzkiewicz and Z. Hubicki, J. Hazard. Mater. 164, 502 (2009).

    Article  CAS  PubMed  Google Scholar 

  35. D. Shao, J. Hu, C. Chen, G. Sheng, X. Ren, and X. Wang, J. Phys. Chem. C 114, 21524 (2010).

    Article  CAS  Google Scholar 

  36. J. Zhang, J. Han, M. Wang, and R. Guo, J. Mater. Chem. A 5, 4058 (2017)

    Article  CAS  Google Scholar 

  37. I. Azni, The Environmentalist 23, 329 (2003).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Génie des Procédés et Chimie des Solutions, Université de Mustapha Stambouli Mascara, Bp 763, Mascara, 29000, Algeria

    A. Belalia, A. Zehhaf & A. Benyoucef

Authors
  1. A. Belalia
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Zehhaf
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Benyoucef
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. Belalia.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Belalia, A., Zehhaf, A. & Benyoucef, A. Preparation of Hybrid Material Based of PANI with SiO2 and Its Adsorption of Phenol from Aqueous Solution. Polym. Sci. Ser. B 60, 816–824 (2018). https://doi.org/10.1134/S1560090418060039

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1560090418060039

Search

Navigation